Ceramics and glasses

Which statement about the relation between piezoelectricity and ferroelectricity is correct?

  1. AAll piezoelectrics are ferroelectrics
  2. BAll ferroelectrics are piezoelectric, but some piezoelectrics, such as quartz, are not ferroelectric
  3. CEven crystals with a center of symmetry become piezoelectric under a strong enough electric field
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Answer: B. All ferroelectrics are piezoelectric, but some piezoelectrics, such as quartz, are not ferroelectric

Piezoelectricity is the property of developing polarization under mechanical stress and, conversely, deforming in an electric field; it requires a crystal without a center of symmetry. Ferroelectrics are crystals with a spontaneous polarization whose direction can be reversed by an electric field; they lack a center of symmetry and so are always piezoelectric. Quartz (α-quartz), by contrast, lacks a center of symmetry and is piezoelectric, but has no spontaneous polarization and so is not ferroelectric. In crystals with a center of symmetry, no first-order piezoelectric effect appears however strong the field (electrostriction, proportional to the square of the field, is a separate effect). Ferroelectric ceramics such as PZT and BaTiO₃ are poled to align the polarization before use as piezoelectric elements.

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