Corrosion and surface treatment

Which statement about stress corrosion cracking is correct?

  1. AIt tends to occur where shot peening has introduced compressive residual stress at the surface
  2. BIt occurs only when the applied stress exceeds the yield stress and the material deforms plastically
  3. CIt occurs when a susceptible material is under tensile stress in a specific corrosive environment
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Answer: C. It occurs when a susceptible material is under tensile stress in a specific corrosive environment

Stress corrosion cracking is the growth of cracks, even at stresses far below the yield stress, when a susceptible material under tensile stress (from external loads or from residual stresses due to welding or working) is exposed to a specific corrosive environment. Classic examples are austenitic stainless steels in hot chloride environments and brass in ammonia-containing environments (season cracking). It is dangerous because the part fractures suddenly with almost no visible corrosion. Removing any one of the three conditions prevents it, so residual stresses are reduced by stress-relief annealing or compressive residual stress is introduced at the surface by shot peening. Compressive stress does not open cracks, so the choice saying it occurs readily where there is compressive residual stress is backward. The choice saying it cannot occur below the yield stress is also wrong.

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More Corrosion and surface treatment questions

  1. Which of the following statements about the corrosion protection of steel sheet is correct?
  2. In a steel pipe, a corrosion current in which iron dissolves as Fe → Fe²⁺ + 2e⁻ flowed at an average of 0.10 A for one year (365 days). Which value is closest to the mass of iron dissolved? Take the molar mass of Fe as 55.85 g/mol and the Faraday constant as 96485 C/mol.
  3. When the corrosion current density of iron is uniformly 1.0 µA/cm² over the whole surface, which value is closest to the rate at which the surface recedes? Assume iron dissolves as Fe²⁺, with a molar mass of 55.85 g/mol, a density of 7.87 g/cm³, a Faraday constant of 96485 C/mol, and one year as 3.15×10⁷ s.
  4. Nickel electroplating is carried out at a current density of 2.0 A/dm² for 30 minutes. Assuming 100% current efficiency, which value is closest to the thickness of the deposit? Take Ni²⁺ + 2e⁻ → Ni, a molar mass of Ni of 58.69 g/mol, a density of 8.90 g/cm³ and a Faraday constant of 96485 C/mol.
  5. At 25 °C, the standard electrode potentials are +0.34 V for Cu²⁺/Cu, −0.44 V for Fe²⁺/Fe and −0.76 V for Zn²⁺/Zn. Which of these three metals is thermodynamically the most easily oxidized (most readily becomes a cation)?