Magnetic materials
What is the main reason permalloy, Fe with about 78% Ni, shows an extremely high permeability?
- AAdding Ni roughly doubles the saturation magnetization relative to pure iron, giving a large flux density quickly even in a weak field
- BIts magnetocrystalline anisotropy and magnetostriction are both nearly zero, so domain walls move and magnetization rotates easily
- CRapid quenching from the melt refines its grains to nanometer sizes, so that the magnetocrystalline anisotropy averages out and cancels
Show answer and explanation
Answer: B. Its magnetocrystalline anisotropy and magnetostriction are both nearly zero, so domain walls move and magnetization rotates easily
A high permeability requires the magnetization to change greatly in a weak field. Magnetization rotation is hindered by magnetocrystalline anisotropy, and if there is magnetostriction, the magnetoelastic energy coupled to internal stresses hinders domain-wall motion. In the Fe–Ni system, at compositions around 80% Ni both the magnetocrystalline anisotropy constant and the magnetostriction constant approach zero, and heat treatment that adjusts the degree of ordering can make the anisotropy even smaller, so a very high permeability is obtained. The saturation flux density of permalloy is considerably lower than that of pure iron (about 2.2 T), so the option citing a saturation magnetization larger than that of pure iron is wrong. Making grains nanometer-sized so that the anisotropy averages out is the idea behind nanocrystalline soft magnetic alloys, not the reason for permalloy.