Nonferrous metals and alloys

In the ASTM designation system for magnesium alloys, what does “AZ91,” widely used for die casting, stand for?

  1. AAn alloy whose main additions are Al and Zn, with about 9 mass% Al and about 1 mass% Zn
  2. BAn alloy whose main additions are Al and Zr, with about 9 mass% Al and about 0.1 mass% Zr
  3. CAn alloy whose main additions are Zn and Al, with about 9 mass% Zn and about 1 mass% Al
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Answer: A. An alloy whose main additions are Al and Zn, with about 9 mass% Al and about 1 mass% Zn

In the ASTM system the two main alloying elements are given one letter each in decreasing order of content (A for Al, Z for Zn, M for Mn, K for Zr, E for rare earths, W for Y and so on), and the numbers that follow are their rounded mass percentages. AZ91 contains about 9% Al and about 1% Zn, and a final letter, as in AZ91D, distinguishes stages of improvement such as tighter control of impurities. The letter for Zr is K, so reading Z as Zr is wrong. The numbers follow the order of the letters, so reading Zn as 9% is also wrong. Al raises strength through solid-solution strengthening and the formation of Mg₁₇Al₁₂ during solidification and precipitation, and it improves fluidity and castability, but too much lowers ductility. AZ31 (about 3% Al and about 1% Zn) is commonly used for wrought products.

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