Crystal defects and diffusion

In a diffusion treatment at a fixed temperature, by what factor must the treatment time be increased to double the depth at which a given concentration is reached?

  1. A2 times
  2. BAbout 1.4 times (√2 times)
  3. C4 times
Show answer and explanation

Answer: C. 4 times

In the error-function solution the concentration depends only on x/2√(Dt), so the depth x at which a given concentration is reached is proportional to √(Dt). At the same temperature D is constant, so doubling the depth requires doubling √t, that is, four times the time. Two times assumes the depth is proportional to time, and √2 times applies the proportionality the wrong way round. The diffusion-distance estimate x ≈ √(Dt) is used in many situations, including carburizing and dopant diffusion. When a deep layer is needed, raising the temperature to increase D is more effective than extending the time.

Report an error

Practice this topic Back to topic

Related calculators

More Crystal defects and diffusion questions

  1. In α-iron at the same temperature, the diffusion coefficient of carbon is many orders of magnitude larger than that of nickel. Which is the main reason?
  2. Which statement about diffusion paths in a polycrystalline metal is correct?
  3. When copper and brass (a Cu-Zn alloy) are bonded and heated, inert markers placed at the original interface move toward the brass side (the Kirkendall effect). What does this phenomenon show?
  4. The Burgers vector of a perfect dislocation in an FCC metal is (a/2)<110>. Which value is closest to its magnitude in aluminum (lattice parameter 0.405 nm)?
  5. Among point defects in ionic crystals, which correctly describes a Frenkel defect?