High-temperature materials and creep

An alloy has a steady-state creep rate that follows ε̇ = Aσⁿexp(−Q/RT) with an activation energy of Q = 300 kJ/mol. If the temperature is raised from 1000 K to 1050 K at the same stress, by roughly what factor does the steady-state creep rate increase? Take R = 8.314 J/(mol·K).

  1. AAbout 1.05 times
  2. BAbout 52 times
  3. CAbout 5.6 times
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Answer: C. About 5.6 times

The ratio of the rates is exp[(Q/R)(1/1000 − 1/1050)]. Since Q/R = 300000/8.314 ≈ 3.61×10⁴ K and (1/1000 − 1/1050) ≈ 4.76×10⁻⁵ K⁻¹, the exponent is about 1.72, and exp(1.72) ≈ 5.6 times. A rise of only 50 K increases the rate more than fivefold because the rate depends exponentially on temperature. The activation energy for high-temperature creep of pure metals is often close to that for self-diffusion, showing that creep is controlled by diffusion. About 52 times is the value obtained by treating the natural exponent as a power of 10, and about 1.05 times takes the ratio of the absolute temperatures as the ratio of the rates.

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  1. A fine-grained polycrystalline metal was creep tested at a low stress at about 0.5 times its melting point (in absolute temperature). The steady-state creep rate was nearly proportional to stress (stress exponent n ≈ 1) and nearly inversely proportional to the cube of the grain size. Which creep mechanism is most likely to be operating?
  2. Which statement about the deformation mechanism map of Ashby and coworkers (with stress normalized by the shear modulus, σ/G, on the vertical axis and homologous temperature T/Tm on the horizontal axis) is correct? Tm is the melting point in absolute temperature.
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  5. Which statement about the γ' phase that provides the high-temperature strength of nickel-based superalloys is correct?