What is Curie temperature?

The temperature at which a ferromagnet (or ferroelectric) loses its spontaneous magnetization (or polarization); above it the material is paramagnetic. About 770 °C for iron and about 358 °C for nickel.

Japanese name: キュリー温度

Curie temperature appears in 4 practice questions across 3 topics, including Magnetic materials, Electronic, magnetic and optical materials, Thermal properties of materials.

Field: Electronic, magnetic and optical materials

The temperature at which spontaneous magnetization vanishes

In a ferromagnet, the exchange interaction aligns the magnetic moments of atoms, producing spontaneous magnetization. As temperature rises, thermal motion disturbs this order, the spontaneous magnetization gradually shrinks, and it reaches zero at the Curie temperature. Above it the material is paramagnetic. Curie temperatures are about 770 °C (1043 K) for iron, about 358 °C for nickel, about 1120 °C for cobalt and about 20 °C for gadolinium; Nd₂Fe₁₄B, the main phase of neodymium magnets, is about 310 °C, and magnetite (Fe₃O₄) about 580 °C.

Behavior above and below the Curie temperature

Above the Curie temperature, the magnetic susceptibility follows the Curie–Weiss law χ = C/(T − θ), rising sharply as the temperature falls toward θ. θ is called the paramagnetic Curie temperature and is close to the Curie temperature. Ferroelectrics behave similarly, with the permittivity becoming very large near the Curie temperature; BaTiO₃ shows a sharp maximum in permittivity at about 120 °C. The Curie temperature is found by measuring the temperature dependence of magnetization with a magnetic balance, or from small anomalies in DSC or thermal expansion.

Common misconceptions

Iron loses its ferromagnetism at 770 °C, but its crystal structure remains BCC α-iron; it changes to FCC only at 912 °C. Iron in this range was once called β-iron, but since no structural change is involved, it is no longer regarded as a separate phase. The temperature at which antiferromagnetic order disappears is called the Néel temperature and is distinguished from the Curie temperature. Permanent magnets suffer irreversible demagnetization from falling coercivity at temperatures far below the Curie temperature, so their maximum service temperatures are set well below it.

Technologies that use the Curie temperature

The abrupt change in magnetism at the Curie temperature is used for temperature control. Rice cookers, for example, once used a mechanism with a temperature-sensitive ferrite that stops being attracted to a magnet at a certain temperature, cutting the heating when the rice is done and the temperature rises. Some soldering irons keep their temperature constant automatically by using a magnetic material in the tip that heats less readily above its Curie temperature. The way magnetite in rocks records the direction of Earth's magnetic field as it cools below its Curie temperature is the basis of paleomagnetic research.

Try it: questions about Curie temperature

When ferromagnetic iron is heated above its Curie temperature (about 770 °C), what happens to its magnetism?

  1. AIt becomes diamagnetic
  2. BIt becomes antiferromagnetic
  3. CIt becomes paramagnetic
Show answer and explanation

Answer: C. It becomes paramagnetic

In a ferromagnet, the magnetic moments of neighboring atoms are aligned in the same direction by the exchange interaction, giving a spontaneous magnetization. As temperature rises, thermal motion disturbs the alignment, and above the Curie temperature the spontaneous magnetization disappears, leaving paramagnetism, a slight magnetization only when an external field is applied. The Curie temperature is about 770 °C for iron, about 358 °C for nickel and about 1120 °C for cobalt. Antiferromagnetism is an ordered state in which neighboring moments align antiparallel, and the temperature at which that order disappears is called the Néel temperature. Diamagnetism is a weak property of all substances and does not appear as a result of ferromagnetism vanishing.

FAQ

What is the difference between the Curie temperature and the Néel temperature?

The Curie temperature is where ferromagnets and ferrimagnets lose their spontaneous magnetization, and the Néel temperature is where antiferromagnets lose their antiparallel order. Above either temperature the material becomes paramagnetic.

Does iron change its crystal structure at 770 °C?

No. 770 °C is the temperature of the magnetic transformation, at which only magnetic order is lost while the structure stays BCC, and it is called the A2 point on the Fe–C phase diagram. The crystal structure changes to FCC at 912 °C (the A3 point).

Does a magnet heated above its Curie temperature recover when cooled?

It becomes ferromagnetic again on cooling, but its magnetic domains point in random directions, so its strength as a magnet remains lost. To use it, it must be magnetized again in a strong field. If its microstructure has changed, its performance will not recover either.

Curie temperature in the explanations

Questions that mention Curie temperature (4)

  1. When ferromagnetic iron is heated above its Curie temperature (about 770 °C), what happens to its magnetism?
  2. What is the main reason a ferromagnet splits into many magnetic domains even without an external field?
  3. What is the main purpose of adding Dy or Tb to neodymium magnets used at high temperatures, such as in electric-vehicle motors?
  4. Which statement correctly explains why the linear thermal expansion coefficient of Fe-36%Ni alloy (Invar) is very small near room temperature, about 1×10⁻⁶ K⁻¹?

Related terms

Magnetic domain Domain wall Magnetocrystalline anisotropy Coercivity Saturation magnetization Maximum energy product Coefficient of linear thermal expansion Invar Indirect-bandgap semiconductor Matthiessen's rule

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