What is Coefficient of linear thermal expansion?

The fractional change in length when the temperature rises by 1 K. It arises from the anharmonicity of the interatomic potential and tends to be smaller in strongly bonded materials with high melting points.

Japanese name: 線膨張係数

Coefficient of linear thermal expansion appears in 10 practice questions across 6 topics, including Thermal properties of materials, Thin films, surfaces and nanomaterials, Ceramics and glasses.

Field: Thermal properties of materials

Try it: questions about Coefficient of linear thermal expansion

A ceramic has a flexural strength of 300 MPa, a Young's modulus of 380 GPa, a Poisson's ratio of 0.22 and a coefficient of linear thermal expansion of 8.0×10⁻⁶ K⁻¹. Which value is closest to the rough temperature difference at which thermal shock from rapid quenching begins to crack it, ΔTc = σf(1 − ν)/(Eα)?

  1. AAbout 77 K
  2. BAbout 99 K
  3. CAbout 127 K
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Answer: A. About 77 K

Eα = 380×10⁹ × 8.0×10⁻⁶ = 3.04×10⁶ Pa/K and σf(1 − ν) = 300×10⁶ × 0.78 = 2.34×10⁸ Pa, so ΔTc = 2.34×10⁸/(3.04×10⁶) ≈ 77 K. About 99 K forgets to multiply by (1 − ν), and about 127 K divides by (1 − ν) instead. Thermal shock resistance is greater the higher the strength and the lower the Young's modulus and thermal expansion coefficient. Fused silica, with a very small thermal expansion coefficient of about 0.5×10⁻⁶ K⁻¹, is extremely resistant to thermal shock. A high thermal conductivity also helps, because it keeps the temperature difference between the surface and the interior small.

An aluminum film (Young's modulus 70 GPa, Poisson's ratio 0.35, linear thermal expansion coefficient 23×10⁻⁶ K⁻¹) on a silicon substrate (linear thermal expansion coefficient 2.6×10⁻⁶ K⁻¹) is cooled from a stress-free 125 °C to 25 °C. Assuming the substrate is sufficiently thick, what are the sign and magnitude of the thermal stress in the film, σ = EΔαΔT/(1 − ν)?

  1. ACompressive, about 220 MPa
  2. BTensile, about 143 MPa
  3. CTensile, about 220 MPa
Show answer and explanation

Answer: C. Tensile, about 220 MPa

Δα = 23×10⁻⁶ − 2.6×10⁻⁶ = 20.4×10⁻⁶ K⁻¹ and ΔT = 100 K, so σ = 70×10⁹ × 20.4×10⁻⁶ × 100/(1 − 0.35) ≈ 2.2×10⁸ Pa, about 220 MPa. On cooling, aluminum tries to shrink more than silicon, but constrained by the substrate it cannot, so the film is pulled into tension. Calling it compressive gets the sign wrong. About 143 MPa forgets to divide by (1 − ν). The film is in a biaxial stress state, constrained simultaneously in both in-plane directions, so the biaxial modulus E/(1 − ν) must be used. Thermal stresses like this cause stress migration and voids in interconnects.

Coefficient of linear thermal expansion in the explanations

Questions that mention Coefficient of linear thermal expansion (10)

  1. A ceramic has a flexural strength of 300 MPa, a Young's modulus of 380 GPa, a Poisson's ratio of 0.22 and a coefficient of linear thermal expansion of 8.0×10⁻⁶ K⁻¹. Which value is closest to the rough temperature difference at which thermal shock from rapid quenching begins to crack it, ΔTc = σf(1 − ν)/(Eα)?
  2. An aluminum film (Young's modulus 70 GPa, Poisson's ratio 0.35, linear thermal expansion coefficient 23×10⁻⁶ K⁻¹) on a silicon substrate (linear thermal expansion coefficient 2.6×10⁻⁶ K⁻¹) is cooled from a stress-free 125 °C to 25 °C. Assuming the substrate is sufficiently thick, what are the sign and magnitude of the thermal stress in the film, σ = EΔαΔT/(1 − ν)?
  3. A thermal oxide film (SiO₂, linear thermal expansion coefficient about 0.5×10⁻⁶ K⁻¹) is grown on a silicon substrate at high temperature and cooled to room temperature. Taking the linear thermal expansion coefficient of silicon as about 2.6×10⁻⁶ K⁻¹, what stress develops in the oxide film due to the difference in thermal expansion?
  4. Which statement correctly explains why the linear thermal expansion coefficient of Fe-36%Ni alloy (Invar) is very small near room temperature, about 1×10⁻⁶ K⁻¹?
  5. According to the Grüneisen relation, the volume expansion coefficient of a solid is roughly proportional to its constant-volume heat capacity. Which statement correctly describes the linear expansion coefficient of an insulator at low temperatures near absolute zero?
  6. Which correctly describes the properties of a metal matrix composite (MMC) of an aluminum alloy reinforced with SiC particles?
  7. Which ordering of linear thermal expansion coefficients near room temperature, from largest to smallest, is correct?
  8. Red-hot quartz glass (fused silica) rarely cracks when dropped into water, whereas soda-lime glass cracks easily. What is the main reason for the high thermal shock resistance of quartz glass?
  9. How do the structure and properties of SiO₂ glass change when Na₂O is added?
  10. Which statement about the structure of a thermal barrier coating (TBC) applied to gas turbine blades is correct?

Related terms

Thermal stress Young's modulus Invar Curie temperature Debye temperature Metal matrix composite Fracture toughness Non-bridging oxygen Glass transition temperature Thermal barrier coating

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