High-temperature materials and creep

A heat flux of 1.0 MW/m² passes uniformly through the thickness of the top coat of a thermal barrier coating (thickness 250 µm, thermal conductivity 1.2 W/(m·K)). Treating it as steady one-dimensional heat conduction, which is closest to the temperature difference between the two faces of the top coat?

  1. AAbout 300 K
  2. BAbout 21 K
  3. CAbout 208 K
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Answer: C. About 208 K

From Fourier's law q = kΔT/L, ΔT = qL/k = (1.0×10⁶ × 250×10⁻⁶)/1.2 ≈ 208 K. That a coating only about 0.25 mm thick can lower the metal temperature by about 200 K is the benefit of a thermal barrier coating. The creep strength of nickel-based superalloys is sensitive to temperature, so this temperature difference strongly affects the life and the allowable gas temperature. About 300 K multiplies by the thermal conductivity instead of dividing, and about 21 K converts the thickness as 25 µm, an order of magnitude too small. The lower the thermal conductivity and the thicker the coating, the larger the temperature difference, but thicker coatings spall more easily under thermal stress, so the thickness is limited.

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More High-temperature materials and creep questions

  1. Which statement about the three stages of a creep curve (strain versus time) measured at constant load and temperature is correct?
  2. The steady-state creep rate of a heat-resistant alloy follows the power law ε̇ = Aσⁿexp(−Q/RT) with a stress exponent of n = 5. If the stress is raised by 20% at the same temperature, by roughly what factor does the steady-state creep rate increase?
  3. An alloy has a steady-state creep rate that follows ε̇ = Aσⁿexp(−Q/RT) with an activation energy of Q = 300 kJ/mol. If the temperature is raised from 1000 K to 1050 K at the same stress, by roughly what factor does the steady-state creep rate increase? Take R = 8.314 J/(mol·K).
  4. A fine-grained polycrystalline metal was creep tested at a low stress at about 0.5 times its melting point (in absolute temperature). The steady-state creep rate was nearly proportional to stress (stress exponent n ≈ 1) and nearly inversely proportional to the cube of the grain size. Which creep mechanism is most likely to be operating?
  5. Which statement about the deformation mechanism map of Ashby and coworkers (with stress normalized by the shear modulus, σ/G, on the vertical axis and homologous temperature T/Tm on the horizontal axis) is correct? Tm is the melting point in absolute temperature.