Strengthening mechanisms and dislocations
Which statement about the characteristics of dislocations shearing through precipitates with an ordered structure, such as the γ' phase (an L1₂ ordered phase) in Ni-based superalloys, is correct?
- AIn an ordered phase the period of the atomic arrangement is half that of the matrix, so a matrix dislocation splits into two partial dislocations inside the precipitate with a twin between them
- BOrdered precipitates are incoherent with the matrix and are never sheared by dislocations, so dislocations bow out and pass between particles of every size
- CA single dislocation that cuts the precipitate leaves an antiphase boundary with the atomic arrangement out of step, so a second dislocation follows to remove it and dislocations move in pairs
Show answer and explanation
Answer: C. A single dislocation that cuts the precipitate leaves an antiphase boundary with the atomic arrangement out of step, so a second dislocation follows to remove it and dislocations move in pairs
In an ordered phase, atoms of different kinds sit on specific sites. When a perfect dislocation of the FCC matrix, (a/2)<110>, cuts a precipitate, the pairing of atoms above and below the slip plane is shifted, creating an antiphase boundary (APB), and its energy is the resistance to shearing. In the ordered phase the original arrangement is restored only after a shift of a<110>, so a second dislocation with the same Burgers vector follows to remove the APB, and the dislocations move as a coupled pair, a superdislocation. The period of the ordered arrangement is longer than that of the matrix, not half of it. γ' is coherent with the matrix, so while small it is normally sheared, and the option claiming it is incoherent and never sheared is also wrong. Precipitating a large amount of γ' with a high APB energy is the key to the high-temperature strength of superalloys.
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