What is Dislocation?

A defect in which the arrangement of atoms in a crystal is disturbed along a line. Metals deform plastically as dislocations move on slip planes. There are edge, screw and mixed dislocations.

Japanese name: 転位

Dislocation appears in 19 practice questions across 8 topics, including High-temperature materials and creep, Heat treatment and metallic materials, Crystal defects and diffusion.

Field: Crystal defects and diffusion

Dislocations make metals weak

The theoretical shear strength needed to shift an entire plane of atoms at once is estimated at about one tenth of the shear modulus, yet real metals yield at stresses a thousandth of that or less. Dislocations explain this large gap. With a dislocation present, there is no need to break atomic bonds all at once; the crystal slips by rearranging bonds a few at a time near the dislocation line, much as moving a ruck in a carpet shifts the whole carpet. How easily a metal deforms plastically is therefore determined by how easily its dislocations move.

Edge and screw dislocations

The type of dislocation is determined by the relation between the Burgers vector b, which gives the magnitude and direction of slip, and the direction of the dislocation line. An edge dislocation has the form of an inserted extra half-plane of atoms, with b perpendicular to the line. In a screw dislocation the atomic planes connect like a spiral staircase, with b parallel to the line. Most dislocations are mixed dislocations combining the two. An edge dislocation has a unique slip plane and, at high temperature, can climb up or down by absorbing or emitting vacancies. A screw dislocation can cross-slip onto another slip plane.

Strengthening means obstructing dislocations

Most strengthening methods for metals work by obstructing dislocation motion. Solid-solution strengthening stops dislocations with the strain fields of solute atoms, precipitation hardening with fine precipitates, grain refinement with grain boundaries, and work hardening with entanglement of dislocations among themselves. Cold working raises the dislocation density from about 10¹⁰ m⁻² to about 10¹⁵ m⁻², increasing strength while lowering ductility. Conversely, when recovery and recrystallization occur during annealing, the dislocation density falls and softness and ductility return.

Observation and effects in semiconductors

Dislocations can be observed directly by TEM as lines of diffraction contrast caused by strain. At a surface, etching forms etch pits where dislocations meet the surface, and counting their density gives the dislocation density. Silicon wafers are made essentially dislocation-free, but if dislocations are introduced during processing, for example by thermal stress, they increase leakage current and become sites for precipitation of metal impurities. When a film with a different lattice parameter is grown, misfit dislocations form at the interface to relax the strain, and threading dislocations may remain in the film.

Try it: questions about Dislocation

Which correctly describes the relation between the Burgers vector and the dislocation line of an edge dislocation?

  1. AThey are perpendicular to each other
  2. BThey are parallel to each other
  3. CThey always make an angle of 45°
Show answer and explanation

Answer: A. They are perpendicular to each other

An edge dislocation has the form of an extra half-plane of atoms inserted into the crystal, and its Burgers vector b is perpendicular to the dislocation line. An edge dislocation glides in the direction of b, and its slip plane is uniquely defined as the plane containing both b and the line. b is parallel to the line in a screw dislocation; because a screw dislocation has no unique slip plane, it can cross-slip onto another slip plane. Most real dislocations are mixed dislocations in between, with the proportions of edge and screw character changing continuously along the line, so there is no fixed 45°.

The Burgers vector of a perfect dislocation in an FCC metal is (a/2)<110>. Which value is closest to its magnitude in aluminum (lattice parameter 0.405 nm)?

  1. AAbout 0.405 nm
  2. BAbout 0.351 nm
  3. CAbout 0.286 nm
Show answer and explanation

Answer: C. About 0.286 nm

The magnitude of (a/2)<110> is (a/2) × √(1² + 1² + 0²) = a/√2, so 0.405/1.414 ≈ 0.286 nm. This equals the nearest-neighbor distance in FCC; dislocations take the shortest lattice translation vector along the close-packed direction as their Burgers vector. About 0.405 nm is the lattice parameter itself (a translation along <100>), which is unfavorable because the dislocation energy is proportional to b². About 0.351 nm applies the BCC (a/2)<111>, that is, √3a/2. The elastic energy per unit length of a dislocation is about Gb²/2, so dislocations with smaller b are more stable.

FAQ

How do dislocations multiply?

During plastic deformation they multiply by mechanisms such as the Frank–Read source, in which a dislocation pinned at both ends bows out and generates loop after loop. The dislocation density therefore increases as working proceeds, causing work hardening.

How are dislocations and the Burgers vector related?

If you make a closed circuit around a dislocation, a closure failure remains compared with a perfect crystal. This is the Burgers vector, which gives the amount and direction by which the crystal is displaced when the dislocation passes.

Why do dislocations move with difficulty in ceramics?

In ionic bonding, slip must avoid bringing ions of the same sign together, and in covalent bonding the bonds are strongly directional, so slip systems are limited and the Peierls stress is large. At room temperature ceramics therefore fracture in a brittle manner before deforming plastically.

Dislocation in the explanations

Questions that mention Dislocation (19)

  1. Which correctly describes the relation between the Burgers vector and the dislocation line of an edge dislocation?
  2. The Burgers vector of a perfect dislocation in an FCC metal is (a/2)<110>. Which value is closest to its magnitude in aluminum (lattice parameter 0.405 nm)?
  3. Which statement about the Young's modulus of steel is correct?
  4. Which material shows a distinct ductile-to-brittle transition at low temperatures?
  5. Which is the correct sequence for precipitation hardening an Al-Cu alloy (duralumin type)?
  6. Which statement about substitutional solid-solution strengthening is correct?
  7. A copper wire 10.0 mm in diameter is drawn down to 8.0 mm. What is the percent cold work (reduction in area)?
  8. Which statement about recrystallization when a cold-worked metal is heated is correct?
  9. Which pair of solute elements forms interstitial solid solutions in iron?
  10. Which correctly describes recovery, which occurs when a cold-worked metal is heated to a temperature too low for recrystallization?
  11. Which correctly describes the mechanism of superelasticity in the Ni-Ti alloy (about 50 at%Ni) used for orthodontic wires and stents? The service temperature is above the reverse transformation finish temperature Af.
  12. Which statement correctly describes the initiation of fatigue cracks when a stress amplitude below the yield stress is repeatedly applied to a metal with a smooth surface?
  13. A Zr-based bulk metallic glass has a yield strength of 1.8 GPa and a Young's modulus of 90 GPa. Which correctly pairs the elastic strain limit estimated as σy/E with its comparison to crystalline metallic materials?
  14. Which statement about plastic deformation of metallic glasses at room temperature is correct?
  15. Which statement about the three stages of a creep curve (strain versus time) measured at constant load and temperature is correct?

Related terms

Young's modulus Recrystallization Recovery Creep Burgers vector Metallic glass Work hardening Diffusion creep Power-law creep Nickel-based superalloy

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