What is Dislocation?
A defect in which the arrangement of atoms in a crystal is disturbed along a line. Metals deform plastically as dislocations move on slip planes. There are edge, screw and mixed dislocations.
Japanese name: 転位
Dislocation appears in 19 practice questions across 8 topics, including High-temperature materials and creep, Heat treatment and metallic materials, Crystal defects and diffusion.
Field: Crystal defects and diffusion
Edge and screw dislocations
The type of dislocation is determined by the relation between the Burgers vector b, which gives the magnitude and direction of slip, and the direction of the dislocation line. An edge dislocation has the form of an inserted extra half-plane of atoms, with b perpendicular to the line. In a screw dislocation the atomic planes connect like a spiral staircase, with b parallel to the line. Most dislocations are mixed dislocations combining the two. An edge dislocation has a unique slip plane and, at high temperature, can climb up or down by absorbing or emitting vacancies. A screw dislocation can cross-slip onto another slip plane.
Observation and effects in semiconductors
Dislocations can be observed directly by TEM as lines of diffraction contrast caused by strain. At a surface, etching forms etch pits where dislocations meet the surface, and counting their density gives the dislocation density. Silicon wafers are made essentially dislocation-free, but if dislocations are introduced during processing, for example by thermal stress, they increase leakage current and become sites for precipitation of metal impurities. When a film with a different lattice parameter is grown, misfit dislocations form at the interface to relax the strain, and threading dislocations may remain in the film.
FAQ
How do dislocations multiply?
During plastic deformation they multiply by mechanisms such as the Frank–Read source, in which a dislocation pinned at both ends bows out and generates loop after loop. The dislocation density therefore increases as working proceeds, causing work hardening.
How are dislocations and the Burgers vector related?
If you make a closed circuit around a dislocation, a closure failure remains compared with a perfect crystal. This is the Burgers vector, which gives the amount and direction by which the crystal is displaced when the dislocation passes.
Why do dislocations move with difficulty in ceramics?
In ionic bonding, slip must avoid bringing ions of the same sign together, and in covalent bonding the bonds are strongly directional, so slip systems are limited and the Peierls stress is large. At room temperature ceramics therefore fracture in a brittle manner before deforming plastically.