What is Recrystallization?
The phenomenon in which new strain-free grains nucleate and grow when a metal storing deformation strain is heated. Strength decreases and ductility is restored.
Japanese name: 再結晶
Recrystallization appears in 6 practice questions across 4 topics, including Heat treatment and metallic materials, Metals and alloys, Magnetic materials.
Field: Metals and alloys
Driving force and how nuclei form
The driving force for recrystallization is the energy of dislocations stored by working. On heating, in regions of high strain, some of the subgrains formed by recovery grow faster than their surroundings and become new grains with high-angle boundaries (recrystallization nuclei). These grains spread by migrating their boundaries into the surrounding dislocation-rich structure, until the whole deformed structure is eventually replaced by grains with little strain. The recrystallized fraction follows an S-shaped curve with time, with a slow start, rapid progress and a slow finish, and is often described by the Johnson–Mehl–Avrami–Kolmogorov (JMAK) equation X = 1 − exp(−ktⁿ).
Recrystallization temperature and degree of working
The recrystallization temperature is usually defined as the temperature at which recrystallization is complete in 1 hour, and a rough guide is 0.3–0.5 of the melting point in absolute temperature. It is lower for higher purity; for example, high-purity copper recrystallizes at about 120 °C, about 0.3 of its melting point. Small amounts of solute hinder boundary migration and raise the recrystallization temperature substantially. Heavier working increases the stored energy and the number of nuclei, which lowers the recrystallization temperature and makes the recrystallized grains finer. The time to complete recrystallization depends strongly on temperature, and a small increase in temperature shortens it greatly.
Distinguishing grain growth and secondary recrystallization
If heating continues after recrystallization is complete, large grains consume small ones to reduce grain-boundary energy. Its driving force is grain-boundary energy, making it a separate stage from recrystallization, which is driven by stored energy. The phenomenon in which only some grains become abnormally large is called secondary recrystallization (abnormal grain growth); in grain-oriented electrical steel, normal grain growth is suppressed by precipitates and only Goss-oriented grains are allowed to recrystallize secondarily, aligning the orientation. Freshly recrystallized grains are also often biased toward particular orientations (recrystallization texture), which affects sheet formability.
FAQ
What fraction of the melting point is the recrystallization temperature?
A rough guide is 0.3–0.5 of the melting point in absolute temperature. However, it varies greatly with purity, degree of working and heating time, so the value for each material needs to be confirmed by experiment.
Does recrystallization change the crystal structure?
No. Recrystallization replaces highly strained grains with less strained ones within the same phase. It is different from changes that alter the crystal structure, such as the transformation of steel to austenite.
What is the critical strain for recrystallization?
It is the minimum degree of working needed for recrystallization, often a few %. Annealing after working near this level produces few nuclei, so the grains become very coarse, causing surface roughening (orange peel) and a loss of strength.