What are Columnar grains?

In the solidification of castings, elongated grains that grow inside the surface chill zone in the direction opposite to heat flow. Equiaxed grains form in the center.

Japanese name: 柱状晶

Columnar grains appears in 3 practice questions across 2 topics, including High-temperature materials and creep, Metals and alloys.

Field: Metals and alloys

How columnar grains form: competitive growth

Not every one of the fine chill grains formed at the mold wall grows inward. In cubic metals, dendrites grow fastest along <100>, and grains whose <100> lies closest to the direction opposite to heat flow (the direction of the temperature gradient) advance furthest. Poorly oriented grains are overtaken by their neighbors and stop growing, so the number of grains decreases with distance inward, leaving a zone of elongated grains with aligned <100>. The texture of the columnar zone, whose properties differ with direction, is a result of this competitive growth.

The columnar-to-equiaxed transition

Whether columnar grains give way to equiaxed grains partway through solidification (the CET, columnar-to-equiaxed transition) is determined by the temperature gradient G and growth rate V at the solidification front and by the alloy composition. The smaller G and the larger V, and the more solute, the more the liquid ahead of the front is constitutionally undercooled and the more easily new nuclei form, favoring the switch to equiaxed grains. Conversely, raising the pouring temperature (increasing the superheat) remelts crystal fragments in the liquid, lengthening the columnar zone. Controlling the position of the CET is central to designing cast structures.

Weaknesses of columnar grains and remedies

The columnar zone has mechanical properties that differ with direction, and solute, impurities and shrinkage cavities tend to collect on the central plane where columnar grains growing from both sides meet (centerline segregation). In continuous casting of steel, electromagnetic stirring is therefore used to move the liquid and break off columnar tips, increasing the fraction of equiaxed grains. In aluminum alloys, Al-Ti-B grain refiners are added to multiply heterogeneous nucleation sites, preventing columnar growth and giving fine equiaxed grains. If a casting is hot worked afterward, the columnar structure is converted into fine grains by recrystallization.

Making columnar grains on purpose: directional solidification

Columnar grains are not only a drawback. Jet engine turbine blades are made by directional solidification, in which the mold is cooled from the bottom so that heat flows in one direction and the blade consists only of columnar grains running along its length. At high temperature, grain boundaries perpendicular to the stress readily become sites of creep fracture, so eliminating them greatly extends life. Furthermore, if a helical passage (a grain selector) is used to select and grow a single grain, the result is a single-crystal blade with no grain boundaries at all. Here too, the fast growth along <100> is put to use.

Try it: questions about Columnar grains

Which sequence of solidification structures is generally seen in the cross section of an ingot made by pouring molten metal into a mold?

  1. AFrom the outside: columnar grains, chill grains, equiaxed grains
  2. BFrom the outside: equiaxed grains, columnar grains, chill grains
  3. CFrom the outside: chill grains, columnar grains, equiaxed grains
Show answer and explanation

Answer: C. From the outside: chill grains, columnar grains, equiaxed grains

When the melt touches the cold mold wall, the large undercooling nucleates many crystals at once, forming a layer of fine equiaxed chill grains at the surface. Next, grains whose orientation favors growth extend selectively in the direction opposite to heat flow toward the mold wall (inward, as heat flows outward), forming a zone of elongated columnar grains pointing toward the center. In the center the temperature gradient becomes small, and equiaxed grains with no preferred direction grow from crystal fragments drifting in the liquid. The choices that start from columnar or equiaxed grains on the outside rearrange this order. Columnar grains have direction-dependent properties, and impurities tend to collect where columnar grains meet, so castings are sometimes inoculated or stirred to increase the equiaxed zone.

At room temperature, refining the grains raises strength (the Hall–Petch relation), but components loaded for long times at high temperature often use coarse grains or single crystals. Which is the correct reason?

  1. ACoarser grains give a higher Young's modulus and so a smaller elastic strain at the same stress, which keeps the creep strain small even under long loading at high temperature
  2. BAt high temperature grain boundaries become stronger than the grain interiors, so reducing the boundaries keeps dislocations from being stopped too much at them and instead lets dislocation motion in the grains relax the stress
  3. CAt high temperature grain boundaries become fast diffusion paths and sliding sites, so grain boundary diffusion creep, grain boundary sliding and void formation on boundaries all become easier the more boundaries there are
Show answer and explanation

Answer: C. At high temperature grain boundaries become fast diffusion paths and sliding sites, so grain boundary diffusion creep, grain boundary sliding and void formation on boundaries all become easier the more boundaries there are

At high temperature, diffusion of atoms along grain boundaries is fast and grain boundary sliding also occurs, so grain boundaries become weak spots. The temperature at which grain boundaries and grain interiors are equally strong is called the equicohesive temperature, and above it the boundaries are the weaker. Diffusion creep (especially Coble creep, inversely proportional to the cube of grain size), grain boundary sliding, and rupture by the nucleation and coalescence of voids on boundaries therefore occur more readily in fine-grained material with many boundaries. That is why coarse grains, columnar grains parallel to the stress, and even single crystals are used in high-temperature components. Young's modulus is set by interatomic bonding and hardly depends on grain size, so it is no advantage of coarse grains. The statement that boundaries become stronger than the interiors at high temperature reverses the relationship.

FAQ

What is the difference between columnar and equiaxed grains?

Columnar grains are elongated in one direction along the heat flow, while equiaxed grains are roughly the same size in every direction. Equiaxed grains show less directional variation in properties and spread segregation more evenly, so they are preferred in many castings.

Why do columnar grains grow along <100>?

Because in cubic metals, anisotropy in the solid–liquid interface energy and in how readily atoms attach makes dendrite trunks grow fastest along <100>. Grains with this direction close to the heat flow survive the competitive growth.

Do columnar grains form in welds too?

Yes. Heat in the weld pool escapes into the surrounding base metal, so columnar grains grow from the fusion boundary toward the weld centerline. Impurities collect on the plane where they meet at the center, which can cause solidification cracking.

Columnar grains in the explanations

Questions that mention Columnar grains (3)

  1. Which sequence of solidification structures is generally seen in the cross section of an ingot made by pouring molten metal into a mold?
  2. At room temperature, refining the grains raises strength (the Hall–Petch relation), but components loaded for long times at high temperature often use coarse grains or single crystals. Which is the correct reason?
  3. Why are directionally solidified columnar-grained or single-crystal nickel-based superalloys used for jet engine turbine blades?

Related terms

Hall–Petch relationship Diffusion creep Young's modulus Nickel-based superalloy Creep Dislocation Brass Recovery Recrystallization Solid-solution strengthening

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