Strengthening mechanisms and dislocations
Which statement about dispersion strengthening with oxide particles, as in copper containing fine Al₂O₃ particles or ODS steels with Y₂O₃ particles dispersed in iron, is correct?
- AIt uses coherent oxides precipitated from the matrix by aging, so the strength can be adjusted just as in precipitation hardening by choosing the solution-treatment and aging temperatures
- BHard oxides that do not dissolve in the matrix and resist coarsening force dislocations to bypass them, so strength tends to remain even at high temperatures where precipitates dissolve or coarsen
- CIt strengthens through the antiphase boundary created when dislocations shear the oxide particles, so larger particles give more strength, and at high temperature the particles dissolve and ductility returns
Show answer and explanation
Answer: B. Hard oxides that do not dissolve in the matrix and resist coarsening force dislocations to bypass them, so strength tends to remain even at high temperatures where precipitates dissolve or coarsen
In dispersion strengthening, oxide particles that hardly dissolve in or react with the matrix are produced and dispersed by internal oxidation or by mechanical alloying, in which powders are mixed intensely. Hard, incoherent particles are not sheared by dislocations and strengthen through the Orowan mechanism. Precipitates lose their strength at high temperature by dissolving or coarsening through Ostwald ripening, but oxide particles change little up to near the melting point, so strength and creep resistance at high temperature are retained. Al₂O₃-dispersed copper is used for welding electrodes and other parts that must resist softening at high temperature, and ODS steels are candidate materials for nuclear fuel cladding. The option about precipitating by aging describes precipitation hardening; oxides do not dissolve in the matrix, so they cannot be solution treated. Antiphase boundaries concern the shearing of ordered precipitates.
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