Surface treatment and tribology

Which statement about nitriding, such as gas nitriding, applied to a nitriding steel containing Al, Cr and Mo is correct?

  1. ANitrogen is diffused in the austenite region at about 900 °C and the part is then quenched to martensite, so it shows larger quench distortion than carburizing
  2. BPure iron and carbon steels without nitride-forming alloying elements let nitrogen diffuse deeper and faster, giving the thickest, hardest layers
  3. CNitrogen diffuses in at about 500–570 °C, in the ferrite region below A₁, and fine nitrides harden the surface without quenching, so distortion is small
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Answer: C. Nitrogen diffuses in at about 500–570 °C, in the ferrite region below A₁, and fine nitrides harden the surface without quenching, so distortion is small

Nitriding introduces nitrogen from the surface, for example by decomposing ammonia, and is carried out at about 500–570 °C, below the A₁ transformation temperature (727 °C). Nitrogen diffuses through ferrite and combines with Al, Cr, Mo, V and similar elements to form fine nitrides, and the surface reaches hardnesses above 1000 HV. With no phase transformation or quenching, dimensional change and distortion are small, so parts can be treated after finish machining. A compound layer of iron nitrides (the white layer) forms at the outermost surface, with a diffusion layer beneath it. In carbon steels without alloying elements, nitrogen may diffuse deeper, but few hard fine nitrides form, so the hardness does not rise much. On the other hand, the case is about 0.1–0.5 mm, thinner than with carburizing, and treatment often takes several tens of hours, which are drawbacks.

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