What is Hardenability?
The depth to which martensite can be obtained by quenching (how readily a steel hardens). It increases when alloying elements such as Mn, Cr and Mo shift the nose of the TTT diagram to longer times.
Japanese name: 焼入れ性
Hardenability appears in 2 practice questions across 2 topics, including Heat treatment and metallic materials, Materials processing and joining.
Field: Heat treatment and metallic materials
Critical diameter and the mass effect
The critical diameter expresses hardenability in terms of part size: it is the largest diameter of a round bar whose center becomes 50% martensite. The value for an ideal quench with infinite cooling power is called the ideal critical diameter, and it can be estimated by finding a base value from carbon content and grain size and multiplying by factors for each alloying element. The phenomenon in which even the same steel hardens less readily in thicker parts, because the center cools more slowly, is called the mass effect, and it is larger in low-hardenability carbon steels. Cooling power also depends on the quenchant, such as water, oil or aqueous polymer solutions.
What raises hardenability, and cautions
Alloying elements such as Mn, Cr, Mo and Ni, and tiny amounts of B around 0.001–0.003%, raise hardenability. A coarser austenite grain size raises hardenability by reducing the grain boundary sites for nucleation, but it lowers toughness. Thicker parts need steels with higher hardenability, but too much hardenability makes quench cracking and distortion more likely, and in welding the heat-affected zone becomes hard and prone to cracking. The basic principle is to choose a steel with the minimum hardenability that still hardens to the required depth.
FAQ
Does a steel with higher hardenability become harder?
No. Higher hardenability lets hardening reach deeper, but the maximum hardness of martensite is set mainly by carbon content. At the same carbon content, alloy steels and carbon steels have almost the same as-quenched surface hardness.
What is the mass effect?
It is the phenomenon in which even the same steel hardens less readily in thicker parts because the interior cools more slowly. It is large in low-hardenability carbon steels and small in alloy steels. To harden thick parts through to the center, choose a steel with high hardenability.
Why does a very small amount of boron raise hardenability?
B segregates to austenite grain boundaries and suppresses the nucleation of ferrite there. It is effective at about 0.001–0.003%, and it is used together with elements such as Ti so that it does not combine with nitrogen.