What is Tempering?
A heat treatment that reheats quenched steel to a temperature below the A1 temperature (727 °C). It restores toughness and reduces internal stresses at the cost of some hardness.
Japanese name: 焼戻し
Tempering appears in 4 practice questions across 4 topics, including Heat treatment and metallic materials, Metals and alloys, Surface treatment and tribology.
Field: Heat treatment and metallic materials
Stages of change during tempering
When as-quenched martensite is heated, it changes in stages depending on temperature. As a rough guide, at about 100–250 °C supersaturated carbon precipitates as fine carbides such as ε-carbide and the tetragonal distortion of the lattice decreases. At about 200–300 °C retained austenite decomposes, and above about 250 °C cementite forms and the matrix approaches ferrite. In steels containing Mo, V, W or Cr, fine alloy carbides precipitate above 500 °C, causing secondary hardening, a temporary rise in hardness.
Beware of temper embrittlement
Depending on the tempering temperature, toughness can actually drop. Tempering at about 250–400 °C causes tempered martensite embrittlement, in which carbides precipitate as films at martensite lath boundaries and impact energy falls, so tempering in this range is usually avoided. Also, when Ni–Cr steels and others are cooled slowly through or held in the range of about 375–575 °C, temper embrittlement occurs as impurities such as P, Sb and Sn segregate to prior-austenite grain boundaries. It is prevented by rapid cooling after tempering, reducing impurities, adding Mo and similar measures.
Timing after quenching, and practice
As-quenched steel has large internal stresses and can crack some time after quenching if left standing (delayed cracking), so it is tempered as soon as possible after quenching. Steels with much retained austenite, such as high-speed tool steels, are tempered two or three times at around 550 °C, converting the retained austenite to martensite and then tempering that martensite. For precision parts such as gauges and bearings, where dimensional stability matters, a subzero treatment cooling below 0 °C may be added after quenching before tempering.
FAQ
What is the difference between tempering and annealing?
Tempering reheats quenched steel to a temperature below the A1 point to restore toughness. Annealing usually heats steel above the A1 or A3 point and cools it slowly to soften it or refine its structure, and it does not presuppose quenching.
What is quenching and tempering?
It is a treatment in which quenching is followed by tempering at a high temperature of about 550–650 °C to balance strength and toughness. It gives a tempered martensite structure and is widely applied to shafts and gears of machine structural steels such as S45C and SCM435.
Can tempering make steel harder?
Yes. In tool steels containing Mo, V, W and similar elements, fine alloy carbides precipitate around 500–600 °C, causing secondary hardening. Hardness can also rise when retained austenite transforms to martensite on cooling.