What is Thermal diffusivity?
The quantity α = κ/(ρc), the thermal conductivity divided by the heat capacity per unit volume. It expresses how quickly a change in temperature spreads through a material and has units of m²/s.
Japanese name: 熱拡散率
Thermal diffusivity appears in 2 practice questions across 1 topic, including Thermal properties of materials.
Field: Thermal properties of materials
How it differs from thermal conductivity
Thermal conductivity κ expresses how much heat flows under a temperature gradient, that is, how easily heat flows in a steady state. Thermal diffusivity α = κ/(ρc), by contrast, is the ratio of conducting heat easily to being hard to warm up (the heat capacity per unit volume ρc), and it expresses how quickly a change in temperature spreads. The transient heat conduction equation is ∂T/∂t = α∇²T, so the change of temperature with time is set by α, not by κ alone. A rough time for the temperature to change through a plate of thickness L is L²/α, which can be used to estimate heating and cooling times.
Typical values
Near room temperature, the thermal diffusivity is about 1.1×10⁻⁴ m²/s for copper, about 1×10⁻⁴ m²/s for aluminum, about 1×10⁻⁵ m²/s for carbon steel, about 4×10⁻⁶ m²/s for stainless steel, about 5×10⁻⁷ m²/s for glass, and about 1×10⁻⁷ m²/s for wood and polymers. Diamond exceeds 10⁻³ m²/s. The heat capacity per unit volume differs only by a few times among solids, so thermal diffusivities rank broadly in the same order as thermal conductivities. Gases have low thermal conductivity but also low density, so their thermal diffusivity is larger than that of solid polymers.
Measurement and use
Thermal diffusivity is commonly measured by the laser flash method. A pulse of light is applied to the front of a disk sample, and α is found as α = 0.1388L²/t½ from the time t½ for the temperature rise of the back face to reach half its maximum. Because the sample can be small and measurements can be made up to high temperatures, the thermal conductivity is often obtained by multiplying the measured α by the density and specific heat, as κ = αρc. Thermal diffusivity matters in heat problems that involve time, such as the spread of temperature in welding and heat treatment, the temperature difference between surface and interior on quenching, and estimates of transient heating in semiconductor devices.
FAQ
Does a material with a large thermal conductivity always have a large thermal diffusivity?
Among solids this is often so, but materials with a large heat capacity per unit volume ρc have a small thermal diffusivity for their thermal conductivity. Choose the quantity according to whether the aim is to compare steady heat flow or the speed of temperature change.
How does thermal diffusivity differ from thermal effusivity?
Thermal diffusivity κ/(ρc) expresses how quickly a change in temperature spreads through a material, while thermal effusivity √(κρc) expresses how much heat a surface absorbs when heat is applied to it. The coldness felt on touching and the momentary temperature rise of a surface depend on the effusivity.
Why does thermal diffusivity have the same units, m²/s, as a diffusion coefficient?
Because the transient heat conduction equation ∂T/∂t = α∇²T has the same form as Fick's second law for the diffusion of matter, ∂C/∂t = D∇²C. The spread of temperature can be treated like the diffusion of atoms, with a characteristic distance of √(αt).