What is Deformation mechanism map?
A map with normalized stress and homologous temperature as axes, showing the fields of the mechanism that deforms fastest, such as dislocation glide, power-law creep and diffusion creep.
Japanese name: 変形機構図
Deformation mechanism map appears in 1 practice question across 1 topic, including High-temperature materials and creep.
Field: High-temperature materials and creep
How the map is made
The deformation mechanism map was proposed by Ashby in 1972, and maps for many metals and ceramics were collected in his 1982 book with Frost. Values such as diffusion coefficients, shear modulus, atomic volume and grain size are inserted into the rate equation of each mechanism, such as dislocation glide, power-law creep and diffusion creep, and the rate is calculated for each combination of stress and temperature. Rates of mechanisms that act independently are added, while for mechanisms that act as alternatives the faster one is chosen, and the field of the mechanism with the largest contribution is shaded. A boundary line is the condition at which the rates of two neighboring mechanisms are equal.
What homologous temperature reveals
Using the homologous temperature T/Tm, the absolute temperature divided by the melting point Tm, on the horizontal axis lets the high-temperature behavior of materials with different melting points be compared on the same scale. As a guide, creep becomes noticeable once T/Tm exceeds about 0.4. Room temperature, 20 °C, is only T/Tm ≈ 0.08 for tungsten (Tm ≈ 3695 K) but as much as about 0.49 for lead (Tm ≈ 601 K). Old lead pipes and roofing sag slowly under their own weight because they are in the creep regime even at room temperature. Conversely, T/Tm = 0.6 for pure Ni corresponds to about 1040 K, or around 760 °C.
Cautions in reading the map
A deformation mechanism map is calculated from model rate equations and literature constants for a fixed grain size and purity. Just as refining the grains enlarges the diffusion creep field, the boundaries move considerably when the microstructure changes, and maps for pure metals cannot be applied directly to alloys containing precipitates. The constants in the rate equations carry errors, so the positions of the boundaries need to be checked by experiment. The map also shows the rate of steady-state deformation and does not tell when fracture occurs. For fracture, separate fracture mechanism maps have been made, showing fields such as cleavage, intergranular fracture and ductile fracture in the same way.
Use in design and materials selection
Placing the service stress and temperature on the map shows which mechanism dominates, and the contours of constant strain rate drawn on the map give a rough idea of the deformation rate. If the point lies in the diffusion creep field, coarser grains help; if it lies in the power-law creep field, precipitates or solute elements that hinder dislocation motion help, so the effective remedy differs. If the point is near a boundary, a slight change in conditions can switch the mechanism, and extrapolation from short tests is likely to fail. In the Earth sciences, maps for rocks and ice are also used to consider the mechanisms of flow in the mantle and in glaciers.
FAQ
What is homologous temperature?
It is the absolute temperature T divided by the melting point Tm (also absolute), T/Tm. The ease of atomic diffusion becomes similar across materials when referred to the melting point, so it is used as a guide to high-temperature deformation. Dividing Celsius temperatures gives a meaningless value, so it must always be calculated with absolute temperatures.
Why is the stress on the vertical axis divided by the shear modulus?
Because the rates of dislocation motion and creep depend not on the stress itself but on how large the stress is relative to the strength of interatomic bonding. Using σ/G, divided by the shear modulus G, lets materials of different strength be compared on the same scale. Maps often also carry a scale of actual stress (MPa) alongside.
What does a boundary line on a deformation mechanism map represent?
It is the combination of stress and temperature at which two neighboring mechanisms produce deformation at the same rate. On the line their contributions are equal, and farther from it one of them dominates. A boundary is not a line where the mechanism switches abruptly; near it, both mechanisms are at work.