What is EDS (energy-dispersive X-ray spectroscopy)?

A method of elemental analysis that measures the energies of characteristic X-rays excited by an electron beam with a semiconductor detector. It measures all elements simultaneously in a short time, but its resolution is lower than that of WDS.

Japanese name: EDS(エネルギー分散型X線分光法)

EDS (energy-dispersive X-ray spectroscopy) appears in 3 practice questions across 1 topic, including Materials characterization (SEM, TEM, XRD, XPS).

Field: Materials characterization (SEM, TEM, XRD, XPS)

Try it: questions about EDS (energy-dispersive X-ray spectroscopy)

Which correctly compares EDS (energy-dispersive spectroscopy) and WDS (wavelength-dispersive spectroscopy) for analyzing characteristic X-rays in SEM and EPMA?

  1. ABecause it needs no analyzing crystal, EDS has better energy resolution and separates overlapping peaks more easily
  2. BWDS has better energy resolution, while EDS can measure many elements simultaneously in a short time
  3. CWDS measures all elements simultaneously with a single detector without moving its crystal, so it is faster than EDS
Show answer and explanation

Answer: B. WDS has better energy resolution, while EDS can measure many elements simultaneously in a short time

EDS measures X-ray energies directly with a semiconductor detector, so it acquires the peaks of all elements simultaneously in a short time and is easily attached to an SEM. Its energy resolution is only about 130 eV, however, so it has difficulty separating close peaks such as Si Kα and W Mα, or S Kα and Mo Lα. WDS selects wavelengths by Bragg reflection from analyzing crystals, so its resolution is about 10 eV, an order of magnitude better, and it is also superior for detecting trace elements and for quantitative accuracy; but it takes time because the analyzing crystal angle must be scanned for each element. The choices saying that EDS has the better resolution or that WDS is the faster swap the characteristics of the two.

EDS (energy-dispersive X-ray spectroscopy) in the explanations

Questions that mention EDS (energy-dispersive X-ray spectroscopy) (3)

  1. Which correctly compares EDS (energy-dispersive spectroscopy) and WDS (wavelength-dispersive spectroscopy) for analyzing characteristic X-rays in SEM and EPMA?
  2. Which correctly describes the information depth of XPS (X-ray photoelectron spectroscopy) and the information it provides?
  3. In semiconductor failure analysis, which technique is best suited to measuring the depth profile of dopant concentration with sensitivity at the ppm to ppb level?

Related terms

SEM (scanning electron microscope) XPS (X-ray photoelectron spectroscopy) SIMS (secondary ion mass spectrometry) XRD (X-ray diffraction) Bragg's law Extinction rules Scherrer equation

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